Open Windows Notepad and write :
[autorun]
icon=iconame.ico
Save as AUTORUN.INF
Then put your icon in the root directory of the CD that you are going to burn Alsoput your AUTORUN.INF in the same directory.
You can also add a label for the cd. If you want that you will have to write in the AUTORUN.INF file :
[autorun]
icon=iconame.ico
label=Label That You Want
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